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Preheat oven to 350 degrees. Lightly grease an 8x8 pan with olive oil or butter.
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Combine sugar cane, 1/2 cup melted butter, eggs and 1 tsp vanilla extract in a large bowl. Mix well, by hand. In a medium bowl, combine 1/3 cup cocoa powder, 1/2 cup flour, salt and baking powder, and stir well. Gradually add in dry ingredients to wet ingredients, 1/2 cup at a time, mixing well by hand after each addition.
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Pour batter into greased pan, and bake in preheated oven for 25 - 30 minutes.
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A few minutes before brownies are done, combine powdered sugar, 3 tbsp softened butter, 3 tbsp cocoa powder and 1 tsp vanilla extract. Beat with an electric mixer until fully incorporated.
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Once brownies are cooked through, and an inserted toothpick comes out clean, spread icing mixture onto brownies, while still hot.
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Then grab a fork, and dig right in! (Contents may be hot).